Two Mn(II)(2)Ln(III)(4) (Ln = Gd, Eu) hexanuclear compounds of p-tert-butylsulfinylcalix[4]arene.

نویسندگان

  • Yanfeng Bi
  • Xiu-Teng Wang
  • Bing-Wu Wang
  • Wuping Liao
  • Xiaofei Wang
  • Hongjie Zhang
  • Song Gao
  • Deqian Li
چکیده

Two 3d-4f heterometallic compounds of p-tert-butylsulfinylcalix[4]arene were synthesized by the solvothermal method and characterized by some hinged double-dumbbell-like subunits in which two perpendicular dumbbell entities were constructed by an in-between isosceles triangle Mn(II)Ln(III)(2), and two tail-to-tail calixarene molecules, and hinged by the lanthanide-sulfinyl group bonding. The magnetic properties of the title compounds were examined.

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عنوان ژورنال:
  • Dalton transactions

دوره 12  شماره 

صفحات  -

تاریخ انتشار 2009